The dimesitylboron group in organic synthesis 8. Preparations of 1,3-diols from oxiranes期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

The dimesitylboron group in organic synthesis 8. Preparations of 1,3-diols from oxiranes

Authors:	Andrew Pelter Gina Bugden Richard Rosser

Affiliation:	Department of Chemistry, University College of Swansea, Singleton Park, Swansea, SA2 8PP U.K.

Abstract:	Alkyldimesitylboranes, yield anions¹, Mes₂B $C$ HR, that on reaction with oxiranes followed by oxidation give 1,3-diols. These anions are thus the operational equivalent of R $C$ HOH. The scope and limitations of the new process are delineated.

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