Synthesis of optically pure α-halo-α′-sulphinyl-ketones |
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| Authors: | Pierfrancesco Bravo Giuseppe Resnati |
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| Affiliation: | CNR - Centro Studio Sostanze Organiche Naturali, Dipartimento di Chimica, Politecnico, Piazza Leonardo da Vinci 32, 20133 Milano, Italy |
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| Abstract: | When optically pure sulphinyl carbanions are reacted at ?75°C with α-chloro or α-bromo carboxylic acid esters addition on the carboxyl group occurs and corresponding α-halo-α′-sulphinyl-ketones are obtained in optically pure form. |
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