Inductivity and charge dispersal in quinuclidinium and bicyclo[2.2.2]octyl-1-cations |
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| Authors: | Rolf Bielmann Cyril A Grob Dieter Küry Yao Guo-Wei |
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| Institution: | Institute of Organic Chemistry University of Basel St. Johanns-Ring 19, CH-4056 Basel, Switzerland. |
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| Abstract: | The pKa of 2-, 3- and 4-substituted quinuclidinium perchlorates and the solvolysis rates of the corresponding bicyclo2.2.2]octyl-l-p-nitrobenzenesulfonates reveal the dispersal of charge in ammonium ions and carbocations. |
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