Convenient synthetic routes to α-oligosiloxanylacrylonitriles |
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| Authors: | Yuhsuke Kawakami Hirofumi Hisada Yuya Yamashita |
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| Affiliation: | Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University, Chikusa, Nagoya 464, Japan |
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| Abstract: | Novel 1,4-elimination reaction of C,N-bis(trimethylsilyl)-C- trimethylsiloxymethylketenimine and retro Diels-Alder reaction of 2-oligosiloxanyl-5-norbornene-2-carbonitrile cleanly gave α-oligosiloxanylacrylonitriles in excellent yield. |
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