Trimethylsilyl trichloroacetate: a new reagent for salt-free silylations |
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| Authors: | James M. Renga Pen-Chung Wang |
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| Affiliation: | Agricultural Products Research & Development The Dow Chemical Company, 2800 Mitchell Drive, Walnut Creek, California 94598 U.S.A.;Central Research, Organic Specialties Laboratory The Dow Chemical Company, M. E. Pruitt Building, Midland, Michigan 48640 U.S.A. |
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| Abstract: | Trimethylsilyl trichloroacetate () is a convenient reagent for the silylation of phenols, carboxylic acids, mercaptans, amides, acetylenes, and β-keto esters, while the reaction of with aldehydes and ketones affords silylated trichloromethyl carbinols (). |
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