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Studies on Chirality Transfer in the [2,3] Sigmatropic Rearrangement of Anions Derived from Trialkylstannylmethyl Allylic Ethers. Stereospecific Synthesis of (2R)-3-Benzyloxy-2-methylpropanol.
Authors:MMark Midland  Young C Kwon
Institution:Department of Chemistry, University of California Riverside, CA 92521, U.S.A.
Abstract:Virtually complete chirality transfer is observed in the 2,3] sigmatropic rearrangement of the anion derived from trialkylstanylmethyl (E)- or (Z)-allylic ethers.
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