Preparation et reactions de Diels et Alder des alcenyl-5(3)-furannones-2 |
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Authors: | C Alexandre F Rouessac B Tabti |
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Institution: | Laboratoire de Synthèse Organique (U.A. CNRS 040482). Faculté des Sciences, Université du Maine, F-72017 Le Mans Cedex France |
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Abstract: | Isomerization of readily available 5-alkenyl 2-(5)-furanones 1 generated from aldehydes and propiolate anion to 5-alkenyl 2-(3)-furanones 2 by base treatment provides a new and convenient access by mild Diels-Alder reaction in water to substituted cyclohexanofuranones. |
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