Adamantanethione and diazomethane; A re-examination |
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| Authors: | Rolf Huisgen Grzegorz Mloston |
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| Institution: | Institut für Organische Chemie der Universität München Karlstr. 23, 8000 München 2, BRD Germany |
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| Abstract: | The title reaction affords the two regioisomeric cycloadducts which were isolated and differ in their rates of nitrogen extrusion; the spiro-1,3,4-thiadiazoline furnishes the adamantanethione S-methylide which undergoes in situ cycloadditions to electron-deficient dipolarophiles. |
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