Stereospecific synthesis of γ-butyrolactones from acyclic vinyl sulfoxides: an asymmetric synthesis of optically pure oak lactones |
| |
| Authors: | JP Marino Roberto Fernández de la Pradilla |
| |
| Institution: | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109 USA |
| |
| Abstract: | The sulfoxide-directed lactonization of several trisubstituted vinyl sulfoxides with dichloroketene proceeds in a completely stereospecific manner. The lactonization of (E) -3 (R) --tolylsulfinyloctene occurs with complete enantiospecificity to produce a precursor for the synthesis of optically pure oak lactones. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
