Studies on Organo-Phosphorus, -Arsenic and -Antimony Polytungstates and Polymolybdates(IX )——Preparation and Properties of o-Aminophenylarsenic Polymolybdates 期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Studies on Organo-Phosphorus, -Arsenic and -Antimony Polytungstates and Polymolybdates(IX )——Preparation and Properties of o-Aminophenylarsenic Polymolybdates

作者姓名：	Liu Benyao Xie Gaoyang and Yihtong Ku(Gu Yidong) (Department of Chemistry Fudan University Shanghai)Wang Xin (Center of Analysis and Measurement Lanzhou University Lanzhou)

作者单位：	Liu Benyao，Xie Gaoyang and Yihtong Ku(Gu Yidong) (Department of Chemistry，Fudan University，Shanghai)Wang Xin (Center of Analysis and Measurement，Lanzhou University，Lanzhou)

摘要：	In order to investigate the influence of organic groups on the types of organoarsenic polymolybdates, o-nitrophenylarsonic acid was reduced to o- aminophenylarsonic acid and then it reacted with sodium molybdate at pH = 3~5. Three new salts were prepared and characterized:( 1 ) (CN3H6)4[(o-NH2C6H4As)2Mo6O24], ( 2 ) Cs4[(o-NH2C6H4As)2Mo6O24], (3) [(CH3)4N]4[(o-NH2C6H4As)2Mo6O24].2H2O. The IR, UV spectra, thermal properties and electrochemical behaviors are reported. It is strange enough that when the o-nitro group was reduced to o-amino group, [(RAs)2Mo6O24]4- type of complexes was formed.
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