Synthesis of 5,6-dihydroxy-2-phenyl-4-pyrimidinecarboxylic acid,methyl ester,a corrected structure |
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Authors: | Townley P Culbertson |
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Abstract: | Pyrolysis of the adduct of benzamide oxime and dimethyl acetylenedicarboxylate leads to 5,6-dihydroxy-2-phenyl-4-pyrimidinecarboxylic acid methyl ester ( 4a ) rather than 4,5-dihydro-α,4-dioxo-2-phenyl-1H-imidazole-5-acetic acid, methyl ester ( 1 ). |
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