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Surface oxygen-assisted Pd nanoparticle catalysis for selective oxidation of silanes to silanols
Authors:Shimizu Ken-ichi  Kubo Takahiro  Satsuma Atsushi
Affiliation:Catalysis Research Center, Hokkaido University, N-21, W-10, Sapporo 001-0021, Japan. kshimizu@cat.hokudai.ac.jp
Abstract:Just add O(2): Based on the fact that an oxygen-adsorbed Pd metal surface shows higher reactivity for water dissociation than a clean Pd surface, carbon-supported Pd nanoparticles (NPs) with surface oxygen atoms were developed as a highly effective and reusable heterogeneous catalyst for selective oxidation of silanes to silanols with water as a green oxidant (see figure).
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