Synthesis, electrochemical properties and self-assembly of a proton-conducting core-shell macromolecule |
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| Authors: | Yin Meizhen Kang Naiwen Cui Guanglei Liu Zhihong Wang Feng Yang Wantai Klapper Markus Müllen Klaus |
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| Institution: | State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, 100029 Beijing, PR China. yinmz@mail.buct.edu.cn |
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| Abstract: | Let the protons flow: The synthesis of a core-shell macromolecule bearing phosphonic acids is presented. The rigid central core serves as a scaffold to stabilize the flexible polymer shells. Pronounced proton conductivity is obtained under humidified conditions. The self-assembly of such dendritic macromolecules by electrostatic interactions on a modified gold substrate is investigated and characterized. |
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