Study of spectral and kinetic characteristics of products of photolysis of a trifunctional compound with light of different wavelengths |
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Authors: | P. P. Levin A. S. Tatikolov N. L. Zaichenko A. I. Shienok L. S. Kol’tsova I. R. Mardaleishvili L. D. Popov S. I. Levchenkov A. A. Berlin |
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Affiliation: | 1.Emanuel Institute of Biochemical Physics,Russian Academy of Sciences,Moscow,Russia;2.Semenov Institute of Chemical Physics,Russian Academy of Sciences,Moscow,Russia;3.Faculty of Chemistry, Southern Federal University, Southern Scientific Center,Russian Academy of Sciences,Rostov-on-Don,Russia |
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Abstract: | Spectral and kinetic characteristics of intermediate products of photolysis of a novel phototrifunctional compound (PTC), whose molecule combines spironaphthoxazine, hydroxyazomethine, and azobenzene fragments, have been studied by microsecond flash photolysis with UV and visible light in toluene and methanol solutions. Three products of PTC photolysis have been detected. It has been found that the efficiency of the photoprocesses substantially depends on the solvent and the wavelength of excitation light. |
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