Luminescent probing of the Tb-C bond in a catalyst of diene polymerization based on ThCl3 · 3(BunO)3PO+Bui
3Al |
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| Authors: | S P Kuleshov R G Bulgakov G L Sharipov G G Bikbaeva L A Safonova A A Gavrilova L I Skarapova |
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| Institution: | (1) Institute of Petrochemistry and Catalysis, Academy of Sciences of Republic Bashkortostan, 141 prosp. Oktyabrya, 450071 Ufa, Russian Federation |
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| Abstract: | The application of chemiluminescence and photoluminescence methods is shown to be promising for studying the mechanism of diene polymerization on Ziegler-Natta catalysts based on organolanthan ide and organoaluminum compounds.The authors are grateful to N. V. Duvakina and Yu. B. Monakov for polymerization of several samples.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 2011–2015, August, 1996. |
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| Keywords: | catalysis lanthanides chemiluminescence photoluminescence |
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