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| 3-甲基丙烯酰胺基-9-乙基咔唑/过硫酸钾体系引发丙烯酰胺聚合 | |
| 引用本文： | 高青雨,关会立,李润明,俞贤达.3-甲基丙烯酰胺基-9-乙基咔唑/过硫酸钾体系引发丙烯酰胺聚合[J].化学研究,2000,11(3):18-20. |
| 作者姓名： | 高青雨 关会立 李润明 俞贤达 |
| 作者单位： | 1. 河南大学润滑与功能材料实验室,开封 475001 中科院兰州化学物理研究所,兰州 730000 2. 河南大学润滑与功能材料实验室,开封 475001 3. 中科院兰州化学物理研究所,兰州 730000 |
| 基金项目： | 河南省自然科学基金，1999150025， |
| 摘 要： | 合成了可聚合芳香叔胺 - 3 甲基丙烯酰胺基 9 乙基咔唑 ,并与过硫酸钾组成氧化还原引发体系引发丙烯酰胺水溶液聚合 ,测定了聚合反应动力学 ,得到了超高分子量的聚丙烯酰胺。 |
| 关 键 词： | 3-甲基丙烯酰胺基-9-乙基咔唑 过硫酸钾 氧化还原引发体系 超高相对分子质量 |
| 文章编号： | 1008-1011(2000)03-0018-03 |
| 修稿时间： | 2000年4月3日 |
Polymerization of Acrylamide Initiated by 3-Methylacrylamide-9-ethylcarbonzole with Persulfate |
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| GAO Qing yu ,GUAN Hui li ,LI Run ming ,YU Xian da.Polymerization of Acrylamide Initiated by 3-Methylacrylamide-9-ethylcarbonzole with Persulfate[J].Chemical Research,2000,11(3):18-20. | |
| Authors: | GAO Qing yu GUAN Hui li LI Run ming YU Xian da |
| Institution: | GAO Qing yu 1,2,GUAN Hui li 1,LI Run ming 1,YU Xian da 2 |
| Abstract: | The polymerization of AM initiated by the MAAECz and potassium persulfate was studied kinetically. The rate equation and overall activation energy for the AM polymerization intiated by the above initiation system was obtained. The UV analysis for PAM initiated by the above initiation system confirmed that the polymerizable MAAECz not only joined the redox initiation but also incorporated into the AM polymer chains. The super high molecule weight of PAM was obtained by using this initiation system. |
| Keywords: | methylacrylamite 9 ethylcarbonzole persulfate redox initiation system super high molecule wight |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |