Ruthenium N‐heterocyclic–carbene catalyzed diarylation of arene C?H bond |
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| Authors: | Sedat Ya?ar Öznur Do?an Ismail Özdemir Bekir Çetinkaya |
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| Institution: | 1. In?nü University, Faculty Science and Art, Department of Chemistry, 44280 Malatya, Turkey;2. Ege University, Faculty Science, Department of Chemistry, 35100 Bornova‐Yzmir, Turkey |
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| Abstract: | Novel ruthenium‐1,3‐dialkylimidazolin‐2‐ylidene complexes ( 2a–e ) have been prepared and characterized by C, H, N analysis, 1H‐NMR and 13C‐NMR. The ortho position of the aromatic ring of pyridyl group substituted aromatic compound was directly arylated with aryl bromides and chlorides in the presence of a catalytic amount of RuCl2(1,3‐dialkylimidazolin‐2‐ylidene)] complexes. Copyright © 2008 John Wiley & Sons, Ltd. |
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| Keywords: | imidazolin‐2‐ylidene N‐heterocyclic carbene C?H activation arylation |
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