| Lipases-Catalyzed Alcoholysis for the Preparation of Chiral 1-or 2- Hydroxyalkanephosphonates |
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| 作者姓名： | 张永辉 李晋峰 |
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| 作者单位： | ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai,Shanghai200032,China |
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| 摘 要： | Enzymatic alcoholysis has been developed for the preparation of some chiral 1-and 2-hydroxyalkanephosphonates with high optical purity.This method ensures the convenient access to the optically pure phosphocarnitine,phosphogabob and phosphomycin.
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| 关 键 词： | 手性化合物 羟基烷烃膦酸酯 醇解 脂肪酶 催化合成 |
Lipases‐Catalyzed Alcoholysis for the Preparation of Chiral 1‐ or 2‐Hydroxyalkanephosphonates |
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| Zhang Yong‐Hui,Li Jin‐Feng,Wang Ke,Yuan Cheng‐Ye.Lipases-Catalyzed Alcoholysis for the Preparation of Chiral 1-or 2- Hydroxyalkanephosphonates[J].Chinese Journal of Chemistry,2003,21(1):4-6. |
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| Authors: | Zhang Yong‐Hui Li Jin‐Feng Wang Ke Yuan Cheng‐Ye |
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| Abstract: | Enzymatic alcoholysis has been developed for the preparation of some chiral 1‐ and 2‐hydroxyalkanephosphonates with high optical purity. This method ensures the convenient access to the optically pure phosphocarnitine, phosphogabob and phosphomycin. |
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| Keywords: | lipase alcoholysis hydroxyalkanephosphonate |
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