Topological and thermodynamic investigations of molecular interactions of aniline and o-toluidine with chloroform |
| |
Authors: | Dimple Sharma JS Yadav Satish Kumar KC Singh VK Sharma |
| |
Institution: | aDepartment of Chemistry, Maharshi Dayanand University, Rohtak-124001, India;bApeejay College of Engineering, Sohna (Gurgaon), Haryana-122001, India |
| |
Abstract: | Molar excess volumes, VE, molar excess enthalpies, HE, and speeds of sound data, u, of chloroform (i) + aniline or o-toluidine (j) binary mixtures have been measured as a function of composition at 308.15 K. Isentropic compressibility changes of mixing, have been determined by employing speed of sound data. Topological investigations of VE data reveals that aniline, chloroform and o-toluidine are associated entities and these (i + j) mixtures contain a 1:1 molecular complex. The IR studies lend further support to the nature and extent of interaction for the proposed molecular entity in the mixtures. HE and values have also been calculated by employing Moelwyn-Huggins concept Polymer 12 (1971) 387] taking topology of the constituents of the mixtures. It has been observed that calculated HE and values compare well with their corresponding experimental values. The observed VE, HE and data have also been analyzed in terms of Flory theory. |
| |
Keywords: | Molar excess enthalpies HE Molar excess volumes VE Isentropic compressibility changes of mixing Connectivity parameter of third degree 3ξ Interaction parameter χ |
本文献已被 ScienceDirect 等数据库收录! |
|