Synthesis of aryl-containing terpenoids based on 1,4-dihydronaphthalene |
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| Authors: | O. S. Kukovinets M. I. Kislitsyn R. A. Zainullin A. A. Mukhamedzyanova F. Z. Galin M. I. Abdullin |
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| Affiliation: | (1) Institute of Organic Chemistry, Ural Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia;(2) Bashkir State University, ul. Mingazheva 100, Ufa, 450014, Bashkortostan, Russia |
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| Abstract: | Successive transformations including oxidation of 1,4-dihydronaphthalene into 1,2,3,4-tetrahydronaphthalen-2-one, Reformatskii reaction of the latter with methyl bromoacetate, ozonolysis of the Reformatsky reaction product, and Emmons olefination of the aldehyde group in methyl 3-oxo-5-(2-formylphenyl)pentanate thus formed gave analogs of highly active dienoate juvenoids having an aromatic ring in their molecules. |
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