Variable coordination chemistry of the phospha(III)guanidinate anion; application as a metal-functionalised phosphine ligand |
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| Authors: | Coles Martyn P Hitchcock Peter B |
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| Institution: | Chemical Laboratories, University of Sussex, Falmer, Brighton, UK BN1 9QJ. m.p.coles@sussex.ac.uk |
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| Abstract: | Structural investigation of Li-complexes of the phospha(III)guanidinate anion Ph2PCNiPr]2]- revealed variable coordination to lithium; synthesis of the dimethyl aluminium compound, (Ph2PCNiPr]2)AlMe2, which behaves as a metal-functionalised phosphine ligand towards platinum, is reported. |
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