Heterometallic CeIII-FeIII-salicylate networks: models for corrosion mitigation of steel surfaces by the 'green' inhibitor,Ce(salicylate)3 |
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| Authors: | Deacon Glen B Forsyth Craig M Behrsing Thomas Konstas Kristina Forsyth Maria |
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| Institution: | School of Chemistry, Centre for Green Chemistry, Monash University, Clayton, Australia. glen.deacon@sci.monash.edu.au |
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| Abstract: | The syntheses and structures of the novel Ce-Fe bimetallic complexes Fe(sal)2(bpy)]2Ce(NO3)(H2O)3].EtOH and Fe(sal)2(bpy)]4Ce2(H2O)11]salH]2.EtOH.3H2O (salH2 = salicylic acid) suggest Fe(3+)-sal2- units and Ce-OC(R)O-Fe bridging contribute to the formation of corrosion inhibitive layers on steel surfaces exposed to Ce(salH)3(H2O)]. |
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