NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation |
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Authors: | Godard Cyril Callaghan Philip Cunningham Jenny L Duckett Simon B Lohman Joost A B Perutz Robin N |
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Affiliation: | Department of Chemistry, University of York, Heslington, York, UK YO10 5DD. |
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Abstract: | Low temperature in-situ UV irradiation of toluene solutions containing bis(alkene)rhodium complexes and parahydrogen in conjunction with NMR monitoring enables the characterisation of unstable eta 2-solvent complexes and dihydrogen activation products. |
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