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Syntheses and spectroscopic studies of spirobifluorene-bridged bipolar systems; photoinduced electron transfer reactions
Authors:Chien Yuh-Yih  Wong Ken-Tsung  Chou Pi-Tai  Cheng Yi-Ming
Affiliation:Department of Chemistry, National Taiwan University, 106 Taipei, Taiwan, ROC.
Abstract:Some 9,9'-spirobifluorene-bridged bipolar systems 1-3 containing 1,3,4-oxadiazole-conjugated oligoaryl and triarylamine moieties have been synthesized, in which 1 exhibits remarkable solvent-polarity dependent fluorescence properties due to a highly efficient photoinduced electron transfer reaction.
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