A new bis(imidazolyl)(alkylthiolate) tripodal ligand and the spontaneous formation of a disulfide-linked,hydroxo-bridged dinuclear zinc complex |
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| Authors: | Karambelkar Vivek V Krishnamurthy Divya Stern Charlotte L Zakharov Lev N Rheingold Arnold L Goldberg David P |
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| Affiliation: | Department of Chemistry, Johns Hopkins University, 3400 N. Charles Street, Baltimore, Maryland 21218, USA. |
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| Abstract: | The new sterically encumbered, tripodal N2S(alkylthiolate) ligand, LIm2SH, has been synthesized and used to prepare [(LIm2S)ZnCH3], which upon protonolysis under acidic conditions leads to the synthesis of a novel dinucleating ligand and a zinc dimer with an unusual structure. |
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