Asymmetric synthesis of (1R,2S,3R)-gamma-methyl-cis-pentacin by a kinetic resolution protocol |
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| Authors: | Bailey Simon Davies Stephen G Smith Andrew D Withey Jonathan M |
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| Affiliation: | Dyson Perrins Laboratory, University of Oxford, South Parks Road, Oxford, UK OX1 3QY. |
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| Abstract: | The asymmetric synthesis of (1R,2S,3R)-3-methyl-2-amino-cyclopentane carboxylic acid has been achieved via kinetic resolution of racemic tert-butyl 3-methyl-cyclopentene-1-carboxylate with homochiral lithium (S)-N-benzyl-N-alpha-methylbenzylamide. |
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