A dynamic (reversible) covalent polymer: radical crossover behaviour of TEMPO-containing poly(alkoxyamine ester)s |
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| Authors: | Otsuka Hideyuki Aotani Koichiro Higaki Yuji Takahara Atsushi |
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| Institution: | Institute for Fundamental Research of Organic Chemistry, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-858, Japan. otsuka@ms.ifoc.kyushu-u.ac.jp |
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| Abstract: | A dynamic covalent polymer incorporating thermally alkoxyamine units in the main chain was synthesized. Due to a radical crossover reaction between the alkoxyamine units, an interchange of the main chains in poly(alkoxyamine ester) was observed on heating. |
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