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New Principles for Glycoside‐Bond Formation |
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| Authors: | Xiangming Zhu Dr. Richard R. Schmidt Prof. Dr. |
| Affiliation: | 1. Centre for Synthesis and Chemical Biology, UCD School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4 (Ireland), Fax: (+353)?1‐716‐2501;2. Fachbereich Chemie, Universit?t Konstanz, Fach 725, 78457 Konstanz (Germany), Fax: (+49)?7531‐883‐135 |
| Abstract: | Meeting the demand for sugars : The importance of oligosaccharides and glycoconjugates in biological systems has stimulated a need to access significant amounts of these compounds. Much effort has been devoted to the stereoselective generation of the key glycosidic bond, both between carbohydrate residues (see scheme) and to the aglycone. Various methodologies are now available for the efficient synthesis of structurally defined complex oligosaccharides and glycoconjugates.  |
| Keywords: | carbohydrates glycoconjugates glycosidation oligosaccharides solid‐phase synthesis |