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Nickel‐Catalyzed Cross‐Coupling of Non‐activated and Functionalized Alkyl Halides with Alkyl Grignard Reagents |
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| Authors: | Oleg Vechorkin Xile Hu Prof?Dr |
| Institution: | Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), ISIC‐LSCI, BCH 3305, 1015 Lausanne (Switzerland), Fax: (+41)?21‐693‐9305 http://isic.epfl.ch/lsci |
| Abstract: | Reacting in the 'Ni'ck of time : The title reaction is realized by using an isolated NiII complex ( 1 ). The catalysis tolerates a wide range of important functional groups that are often incompatible with Grignard reagents in cross‐coupling reactions.  |
| Keywords: | C?C coupling cross‐coupling Grignard reaction homogeneous catalysis nickel |