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A Hydride‐Rich Magnesium Cluster
Authors:Merle Arrowsmith  Michael S Hill Dr  Dugald J MacDougall Dr  Mary F Mahon Dr
Institution:Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY (UK)
Abstract:High‐de‐hydride! A straightforward reaction between a magnesium silylamido/N‐heterocyclic carbene adduct and phenylsilane provides a {Mg4H6} cluster molecule that may be regarded as a combination of two magnesium dihydride and two magnesium monohydride moieties.
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Keywords:amides  carbene ligands  cluster compounds  hydrides  magnesium
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