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Secondary Alkyl Halides in Transition‐Metal‐Catalyzed Cross‐Coupling Reactions
Authors:Alena Rudolph  Mark Lautens Prof. Dr.
Affiliation:Davenport Chemistry Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON, M5S 3H6 (Canada), Fax: (+1)?416‐946‐8185
Abstract:Secondary, but second to none : The use of secondary alkyl halides in transition‐metal‐catalyzed cross‐coupling reactions (see scheme) has advanced significantly over the last five years. Selected examples of these transformations are examined, including mechanistic and stereochemical aspects.
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Keywords:alkyl halides  cobalt  cross‐coupling  iron  nickel
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