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Phase Transformation in Titania Nanocrystals by the Oriented Attachment Mechanism: The Role of the pH Value
Authors:Caue Ribeiro Dr  Cristiano M Barrado Dr  Emerson R de Camargo Prof Dr  Elson Longo Prof Dr  Edson R Leite Prof Dr
Institution:1. EMBRAPA Instrumenta??o Agropecuária, Rua XV de Novembro, 1452‐13560‐970, CP 741, S?o Carlos, SP (Brazil), Fax: (+55)?16‐2107‐2902;2. LIEC/Universidade Federal de S?o Carlos, Departamento de Química, Rod. Washington Luiz km 235‐13565‐905, S?o Carlos, SP (Brazil);3. LIEC/Universidade Estadual Paulista, Instituto de Química, Rua Francisco Degni, s/n, 14800‐900, Araraquara, SP (Brazil)
Abstract:The oriented attachment (OA) mechanism has been investigated as an important process in the formation of anisotropic nanostructures such as depicted. The results showed that the control of a desired phase in this system may be attained by the control of OA mechanism through pH value, obtaining several morphologies.
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Keywords:crystal growth  nanostructures  oriented attachment  phase transitions
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