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Synthesis of 4‐substituted styrene compounds via palladium catalyzed Suzuki–Miyaura reaction using bidentate Schiff base ligands
Authors:Yan Liu  Jinqu Wang
Institution:State Key Laboratory of Fine Chemicals, Institute of Adsorption and Inorganic Membranes, Dalian 116012, People's Republic of China
Abstract:Air‐stable symmetric Schiff base have been synthesized and proved to be efficient ligands for Suzuki–Miyaura reaction between aryl bromides and arylboronic acids using PdCl2(CH3CN)2 as palladium source under aerobic conditions. The coupling reaction proceeded smoothly using N,N‐bis(anthracen‐9‐ylmethylene)benzene‐1,2‐diamine (L7) as ligand to provide 4‐substituted styrene compounds in good yields. Copyright © 2009 John Wiley & Sons, Ltd.
Keywords:Suzuki–  Miyaura reaction  Schiff base  4‐substituted styrene compounds  synthesis
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