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High‐Purity Discrete PEG‐Oligomer Crystals Allow Structural Insight
Authors:Alister C French  Amber L Thompson Dr  Benjamin G Davis Prof
Institution:Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford (UK), Fax: (+44)?1865‐275‐674 users.ox.ac.uk/ndplb0149
Abstract:To great (monodisperse) lengths : An improved synthesis of purer ethylene glycol (EG) oligomers allows access to 16‐ and 32‐mers pure enough for multiple incorporation, and also to the longest (48‐mer) discrete EG oligomer yet reported. The high purity enables the first crystallizations and hence the first glimpses of secondary 310‐helical PEG structures.
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Keywords:helical structures  mass spectrometry  poly(ethylene glycol)  polymers  synthetic methods
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