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Molecular Catalysts that Oxidize Water to Dioxygen
Authors:Xavier Sala  Isabel Romero  Montserrat Rodríguez  Lluís Escriche  Antoni Llobet
Institution:1. Institute of Chemical Research of Catalonia (ICIQ), Av. Pa?sos Catalans 16, 43007 Tarragona (Spain);2. Departament de Química, Universitat de Girona, Campus de Montilivi, 17071 Girona (Spain);3. Departament de Química, Universitat Autònoma de Barcelona, Cerdanyola del Vallès, 08193 Barcelona (Spain)
Abstract:Water into oxygen : A good catalyst for converting water into oxygen is seen as an essential part of any sustainable solar‐energy conversion scheme. Some success has been achieved using molecular complexes as catalysts and the key factors influencing their performance are discussed. The necessity of generating a solid‐state catalytic system is presented and the first attempts to generate supported molecular water‐oxidation catalysts are analyzed.
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Keywords:artificial photosynthesis  heterogeneous catalysis  homogeneous catalysis  oxidation  sustainable chemistry
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