1. IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120 (USA), Fax: (+1)?408‐927‐3310;2. Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (The Netherlands);3. Institute of Bioengineering and Nanotechnology, 31 Biopolis Way, The Nanos, Singapore 138669 (Singapore)
Abstract:
Once around the block : Incorporation of a rigid hydrogen‐bonding benzamide unit, placed at the interface between two polymer blocks, in poly(ethylene glycol) (PEG)–(thio)urea–poly(L ‐lactide) (PLLA) block copolymers transforms the morphology of the block copolymers, from spherical micelles, as formed by PEG‐PLLA diblock copolymers, into nanotubes in solution.