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Low‐Energy‐Electron‐Induced Hydroamination of an Alkene
Authors:Thorben Hamann  Esther Böhler  Petra Swiderek Prof Dr
Institution:Institute of Applied and Physical Chemistry, Universit?t Bremen, Fachbereich 2 (Chemie/Biologie), Leobener Strasse, 28359 Bremen (Germany), Fax: (+49)?421‐218‐4918, http://www.iapc.uni‐bremen.de/swiderek/
Abstract:The smallest catalyst : A new strategy to control chemical synthesis by exposure to low‐energy electrons relies on the electrostatic attraction caused by the soft ionization of one of the reaction partners. This approach was used to induce a reaction between C2H4 and NH3 yielding aminoethane. The reaction resembles a hydroamination except that the electron beam replaces the catalyst used in the organic synthesis.
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Keywords:alkenes  ammonia  electron‐induced reactions  hydroaminations  thermal desorption spectrometry
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