Palladium bis(2,2,6,6‐tetramethyl‐3,5‐heptanedionate) catalyzed alkoxycarbonylation and aminocarbonylation reactions |
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| Authors: | Pawan J Tambade Yogesh P Patil Bhalchandra M Bhanage |
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| Institution: | Department of Chemistry, Institute of Chemical Technology, N. Parekh Marg, Matunga, Mumbai‐ 400 019, India |
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| Abstract: | Palladium bis(2,2,6,6‐tetramethyl‐3,5‐heptanedionate), a structurally well defined O‐containing transition metal complex, is reported to be an efficient catalyst for alkoxycarbonylation and aminocarbonylation reactions under milder operating conditions. The system tolerated the carbonylative coupling of various aryl halides with phenol/alcohol and amines, providing good to excellent yields of desired products under optimized reaction conditions. Copyright © 2009 John Wiley & Sons, Ltd. |
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| Keywords: | alkoxycarbonylation aminocarbonylation aryl halide carbonylation palladium (TMHD)2 complex |
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