|
|||||
|
|
Grafting of Polyfluorene by Surface‐Initiated Suzuki Polycondensation |
|
| Authors: | Tetyana Beryozkina Dr Ksenia Boyko Natalya Khanduyeva Volodymyr Senkovskyy Dr Marta Horecha Ulrich Oertel Dr Frank Simon Dr Manfred Stamm Prof Anton Kiriy Dr |
| Institution: | Department of Nanostructured Materials, Leibniz‐Institut für Polymerforschung Dresden e.V. Hohe Strasse 6, 01069 Dresden (Germany), Fax: (+49)?351‐4658‐294 |
| Abstract: | Graft work : The first surface‐initiated and site‐specific palladium‐catalyzed Suzuki polycondensation that allows selective grafting and patterning of semiconducting and emissive poly9,9‐bis(2‐ethylhexyl)fluorene] ( 1 ) at room temperature is developed (see scheme). The pattering is demonstrated by AFM (see image).  |
| Keywords: | polyfluorene polymerizations surface chemistry Suzuki polycondensation |