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Characterization of Key Intermediates in a Complex Organocatalytic Cascade Reaction Using Mass Spectrometry |
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| Authors: | Wolfgang Schrader Priv.‐Doz. Dr. Peni Purwa Handayani Jian Zhou Dr. Benjamin List Prof. Dr. |
| Affiliation: | Max‐Planck‐Institut für Kohlenforschung, Kaiser Wilhelm‐Platz 1, 45470 Mülheim an der Ruhr (Germany) |
| Abstract: | Chemical scrabble : Mechanistic studies of complex organocatalytic cascade reactions are challenging owing to the presence of many species involved. Electrospray ionization mass spectrometry provides details about a one‐pot quadruple organocatalytic cascade reaction, and allows detailed characterization of the reaction and its key intermediates.  |
| Keywords: | cascade reactions complexe reactions electrospray mass spectrometry iminium catalysis organocatalysis |