Cosolvent‐promoted electrophilic amination of organozinc reagents |
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| Authors: | Tahir Daşkapan Ferhat Yeşilbağ Selçuk Koca |
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| Affiliation: | Ankara University, Science Faculty, Department of Chemistry, 06100 Be?evler, Ankara, Turkey |
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| Abstract: | In this study, we aimed to develop a simple and efficient method for the electrophilic amination of organozinc reagents. For this reason, 12 cosolvents were screened in the electrophilic amination of ordinary organozinc reagents. By the use of a cosolvent, an easily applicable and high‐yielding method for the preparation of arylamines by electrophilic amination of arylzinc reagents was developed. Copyright © 2009 John Wiley & Sons, Ltd. |
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| Keywords: | electrophilic amination organozinc reagents amines cosolvent aminating agent |
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