|
|||||
|
|
Enantiomerically Pure Chiral {Fe28} Wheels |
|
| Authors: | Zhi‐Ming Zhang Dr Yang‐Guang Li Dr Shuang Yao Dr En‐Bo Wang Prof Yong‐Hui Wang Dr Rodolphe Clérac Prof |
| Institution: | 1. Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Ren Min Street No.5268, Changchun, Jilin 130024 (China), Fax: (+86)?431‐85098787;2. CNRS, UPR 8641, Centre de Recherche Paul Pascal (CRPP) Equipe “Matériaux Moléculaires Magnétiques”, 115 avenue du Dr. Albert Schweitzer, Pessac, F‐33600 (France);3. Université de Bordeaux, UPR 8641, Pessac, 33600 (France) |
| Abstract: | Wheels of steel : Two enantiomerically pure chiral {Fe28} wheel‐like aggregates have been synthesized from the acetate buffer solution containing ferric ions and chiral tartrate ligands (see picture). These compounds are the largest chiral ferric aggregates isolated to date.  |
| Keywords: | chirality iron magnetic properties Mö ssbauer spectroscopy tartrate |