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Rational Construction of 2D and 3D Borromean Arrayed Organic Crystals by Hydrogen‐Bond‐Directed Self‐Assembly
Authors:Yong‐Biao Men  Junliang Sun Dr  Zhi‐Tang Huang Prof  Qi‐Yu Zheng Prof
Institution:1. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China), Fax: (+86)?10‐6255‐4449;2. Structural Chemistry and Berzelii Centre EXSELENT on Porous Materials, Stockholm University, 10691 Stockholm (Sweden)
Abstract:Borromean organic networks: The rigid and trigonal pyramidal molecule, 1,3,5‐tris(4‐carboxyphenyl)adamantane (TCA), self‐assembles into a 2D Borromean linked network by hydrogen bonds. Different linkers (methanol, phenazine, 4,4′‐bipyridine, and 4,4′‐azopyridine) result in more complex Borromean networks or a 3D polycatenation network.
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Keywords:Borromean rings  crystal engineering  hydrogen bonds  self‐assembly  topology
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