Synthesis and Structure of Heterodinuclear Rhodium and Iridium Borylene Complexes |
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Authors: | Holger Braunschweig Prof Dr Melanie Forster Fabian Seeler Dr |
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Institution: | Institut für Anorganische Chemie, Julius‐Maximilians‐Universit?t Würzburg, Am Hubland, 97074 Würzburg (Germany), Fax: (+49)?931‐888‐4623 |
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Abstract: | Herein we report on the synthesis and structural characterization of a representative range of novel heterodinuclear bridging rhodium and iridium borylene complexes. The iridium borylene complexes feature an unusual coordination mode of the borylene ligand. Furthermore, the first instance of a heterodinuclear‐bridged borylene compound containing a chromium atom in the three‐membered ring is reported. |
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Keywords: | boron borylene complexes bridging ligands iridium rhodium |
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