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Symmetry versus Minimal Pentagonal Adjacencies in Uranium‐Based Polyoxometalate Fullerene Topologies
Authors:Ginger?E Sigmon  Daniel?K Unruh  Jie Ling  Brittany Weaver  Matthew Ward  Laura Pressprich  Antonio Simonetti Prof  Peter?C Burns Prof
Institution:1. Department of Civil Engineering and Geological Sciences, University of Notre Dame, Notre Dame, IN 46556 (USA), http://petercburns.com;2. Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556 (USA)
Abstract:C U soon : Clusters containing 60, 44, and 36 uranyl peroxide hydroxide polyhedra (see picture) adopt fullerene topologies of maximum symmetry. The largest of these, denoted U60, is topologically identical to C60 with no pentagonal adjacencies and the highest possible symmetry. U44 adopts the topology with maximum symmetry rather than that with the lowest number of pentagonal adjacencies.
image

Keywords:actinides  fullerenes  polyoxometalates  self‐assembly  uranium
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