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An [(NHC)(NHCEWG)RuCl2(CHPh)] Complex for the Efficient Formation of Sterically Hindered Olefins by Ring‐Closing Metathesis
Authors:Tim Vorfalt Dipl‐Ing  Steffen Leuthäußer Dr  Herbert Plenio Prof?Dr
Institution:Anorganische Chemie im Zintl‐Institut, Technische Universit?t Darmstadt, Petersenstrasse 18, 64287 Darmstadt (Germany)
Abstract:NHC with EWGs for RCM : Ruthenium complexes with two N‐heterocyclic carbenes (NHCs), one of them substituted with electron‐withdrawing groups (EWGs), are highly efficient (pre)catalysts for the synthesis of tetrasubstituted olefins and trisubstituted olefins by ring‐closing metathesis reactions (RCM, see scheme).
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Keywords:homogeneous catalysis  N‐heterocyclic carbenes  metathesis  ring‐closing metathesis  ruthenium
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