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Structural Link between Giant Molybdenum Oxide Based Ions and Derived Keggin Structure: Modular Assemblies Based on the [BW11O39]9− Ion and Pentagonal {M′M5} Units (M′=W; M=Mo,W) |
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| Authors: | Nathalie Leclerc‐Laronze Dr. Jérôme Marrot Dr. René Thouvenot Dr. Emmanuel Cadot Prof. |
| Affiliation: | 1. Université de Versailles Saint Quentin, Institut Lavoisier de Versailles, ILV, UMR CNRS 8180, 45 Avenue des Etats‐Unis, 78035 Versailles Cedex (France), Fax: (+33)?1‐3925‐4381;2. Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, Case courrier 42, Université Pierre et Marie Curie, Paris 6, 4, Place Jussieu, 75252 Paris Cedex 05 (France), Fax: (+33)?1‐4427‐3841 |
| Abstract: | Linked to the Pentagon : The addition of molybdate to [HBW11O39]8? ions leads to the formation of mixed pentagonal units {W(Mo5)} and {W(WMo4)} trapped as linkers in the resulting modular assemblies, thus establishing the first link between the conventional Keggin ion derivatives and the giant molybdenum oxide and keplerate ions.  |
| Keywords: | molybdenum polyoxometalates solid‐state structures transition metals tungsten |