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Synthesis,structural characterization and electrochemical recognition of metal ions of two new ferrocenylhydrazone‐based receptors
Authors:Chunjie Qiao  Jie Li  Yan Xu  Shuyan Guo  Xue Qi  Yaoting Fan
Affiliation:Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, People's Republic of China
Abstract:Two new ferrocenylhydrazone‐based receptors FcL1 and FcL2 were prepared and the X‐ray crystal structure of FcL1 was described. The electrochemical studies reveal that the receptor FcL1 is responsive to Hg2+ and Cr3+, whereas, receptor FcL2 only responsive to Hg2+. The maximum electrochemical shift of FcL1 for Cr3+ is about 56 mV. Copyright © 2009 John Wiley & Sons, Ltd.
Keywords:synthesis  structural characterization  electrochemical recognition  receptor
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