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The Antimony‐Based Type I Clathrate Compounds Cs8Cd18Sb28 and Cs8Zn18Sb28 |
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| Authors: | Yi Liu Dr Li‐Ming Wu Prof Dr Long‐Hua Li Shao‐Wu Du Prof Dr John D Corbett Prof Dr Ling Chen Prof Dr |
| Institution: | 1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China), Fax: (+86)?591‐8370‐4947;2. Ames Laboratory, Iowa State University, Ames, IA 50011 (USA) |
| Abstract: | In phase : The title compounds lie in a new region of phase space for such a structure, and have stoichiometries in accord with a classical Zintl phase formulation. The small semiconductor gaps indicated by DFT calculations are also supported by their diamagnetic susceptibilities.  |
| Keywords: | antimony clathrates solid‐state reactions Zintl phases |