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Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In‐Plane Rotational Epitaxial Relationship |
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| Authors: | Shuhei Furukawa Dr. Kenji Hirai Keiji Nakagawa Yohei Takashima Ryotaro Matsuda Dr. Takaaki Tsuruoka Dr. Mio Kondo Dr. Rie Haruki Dr. Daisuke Tanaka Dr. Hirotoshi Sakamoto Satoru Shimomura Osami Sakata Dr. Susumu Kitagawa Prof. |
| Affiliation: | 1. ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo‐ku, Kyoto 600‐8815 (Japan), Fax: (+81)?75‐325‐3572 http://kip.jst.go.jp;2. Institute for Integrated Cell‐Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo‐ku, Kyoto 606‐8501 (Japan);3. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo‐ku, Kyoto 615‐8510 (Japan);4. Research & Utilization Division (Japan), Synchrotron Radiation Research Institute/SPring‐8 and CREST, JST, Kouto, Sayo, Hyogo 679‐5198 (Japan) |
| Abstract: | MOF on MOF: Core–shell porous coordination polymer (PCP) crystals are fabricated at the single‐crystal level by epitaxial growth in solution. Synchrotron X‐ray diffraction measurements unveiled the structural relationship between the shell crystal and the core crystal, where in‐plane rotational epitaxial growth compensates the difference in lattice constant.  |
| Keywords: | coordination polymers crystal growth interfaces metal– organic frameworks microporous materials |